Portugal is 2.1 times larger than Rio de Janeiro (Brazil).
Area: 92,145 km2 Wikipedia
Population: 10,459,806 (2,013) World Bank
Continental Portugal or Mainland Portugal is the part of the territory of Portugal located in the Iberian Peninsula and so in Continental Europe. Continental Portugal is also commonly referred to - by the Portuguese - simply as the Continent. Wikipedia
Rio de Janeiro is one of the 27 states of Brazil. It has the third largest economy of Brazil, with the largest being that of the state of São Paulo, and the second being that of Minas Gerais. The state of Rio de Janeiro is located within the Brazilian geopolitical region classified as the Southeast. Wikipedia